Scheduling and managing events using Outlook.com calendar
When you said outlook UI do you mean the outlook.com website?
are you using a third party email address as your Microsoft account alias?
if so this is normal behavior. The outlook website is not an email client app so it cannot send or receive emails on behalf of your third party email address. The email address you use is simply an alias/ username. Actual email sending and receiving is via the third party email service provider.
let me know if I understand your setup correctly.